Spectroscopic studies on derivatives of aluminium borohydride
Spectrum: Concordia University Research Repository
View Archive Info| Field | Value | |
| Title |
Spectroscopic studies on derivatives of aluminium borohydride
|
|
| Creator |
Davies, N.
Bird, Peter H. Wallbridge, M. G. H. |
|
| Description |
The assignment of group frequencies in the i.r. spectra of derivatives of aluminium borohydride has been made by the use of aluminium borodeuteride. Variations in the spectra with the change of ligand are discussed. The properties of the compounds in solutions have been studied using 1H n.m.r. spectroscopy, and data obtained over a range of temperature indicate that the 1 : 1 adducts with trimethylamine and trimethylphosphine dissociate in solution, and probably exist in equilibrium with both the 1 : 2 adducts, e.g. Al(BH4)3,2NMe3 and free aluminium borohydride
|
|
| Publisher |
Royal Society of Chemistry
|
|
| Date |
1968
|
|
| Type |
Article
PeerReviewed |
|
| Format |
application/pdf
|
|
| Identifier |
http://spectrum.library.concordia.ca/7657/1/Bird_JCSa_1968.pdf
Davies, N. and Bird, Peter H. and Wallbridge, M. G. H. (1968) Spectroscopic studies on derivatives of aluminium borohydride. Journal of the Chemical Society A: Inorganic, Physical, Theoretical (9). pp. 2269-2272. ISSN 0022-4944 |
|
| Relation |
http://dx.doi.org/10.1039/J19680002269
http://spectrum.library.concordia.ca/7657/ |
|